Si-C bond activation in the reaction of first generation Grubbs' catalyst with alkynylsilanes - formation of [Cl(2){P(C(6)H(11))(3)}(2)Ru(=CHCH=CHPh)] anddisiloxanes.

نویسندگان

  • Beata Powała
  • Helmut Fischer
  • Cezary Pietraszuk
چکیده

The first generation Grubbs catalyst [Cl(2){P(C(6)H(11))(3)}(2)Ru=C(H)Ph] reacts efficiently with alkynylsilanes in the presence of water to give the styryl carbene complex [Cl(2){P(C(6)H(11))}(2) Ru=C(CH=CHPh)H] and disiloxane.

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عنوان ژورنال:
  • Dalton transactions

دوره 39 8  شماره 

صفحات  -

تاریخ انتشار 2010